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41.
Cr(Ⅵ)污染土壤的热解还原无害化处理 总被引:4,自引:2,他引:2
提出了用热解还原法对含铬土壤进行无害化处理的新技术,研究了热解温度、热解时间及土壤有机质对铬无害化处理的影响,分析了热解前后土壤中铬的元素形态的变化.同时还探讨了热解还原过程中Cr(Ⅵ)的无害化机制.结果表明,土壤中的有机质在热解还原过程中产生的挥发分对Cr(Ⅵ)的无害化起核心作用;在200~600℃范围内,Cr(Ⅵ)的还原量随着热解温度升高而增大,500.0℃最适合于经济有效地实现Cr(Ⅵ)的热解还原处理;Cr(Ⅵ)的热解还原过程较快.铬的形态分析结果表明,热解后可交换态和碳酸盐结合态铬量大大降低,大部分铬转化成了活性低的残渣态,极大地降低了铬的危害. 相似文献
42.
羧甲基-β-环糊精对土壤中萘的洗脱去除作用 总被引:5,自引:0,他引:5
研究了不同浓度的羧甲基-β-环糊精溶液对不同组分土壤中萘的洗脱去除作用,同非离子表面活性剂脂肪醇聚氧乙烯醚的洗脱去除作用比较,讨论了其对洗脱效果的影响因素.结果表明:羧甲基-β-环糊精溶液对土壤中的萘有较好的洗脱去除效果,20g·1-1的羧甲基-β-环糊精溶液的洗脱率可达90%以上;洗脱液浓度和土壤质地是影响洗脱去除率的主要因素;适当地增加洗脱液浓度对洗脱去除率有显著提高;与脂肪醇聚氧乙烯醚相比,以羧甲基-β-环糊精溶液作为增溶试剂,对土壤中的弱极性有机污染物进行洗脱处理具有更好的效果 相似文献
43.
Global climate change (GCC) is expected to influence the fate, exposure and risks of organic pollutants to wildlife and humans. Multimedia chemical fate models have been previously applied to estimate how GCC affects pollutant concentrations in the environment and biota, but previous studies have not addressed how uncertainty and variability of model inputs affect model predictions. Here, we assess the influence of climate variability and chemical property uncertainty on future projections of environmental fate of six polychlorinated biphenyl congeners under different GCC scenarios using a spreadsheet version of the ChemCAN model and the Crystal Ball® software. Regardless of emission mode, results demonstrate: (i) uncertainty in degradation half-lives dominates the variance of modelled absolute levels of PCB congeners under GCC scenarios; (ii) when the ratios of predictions under GCC to predictions under present day climate are modelled, climate variability dominates the variance of modelled ratios; and (iii) the ratios also indicate a maximum of about a factor of 2 change in the long-term average environmental concentrations due to GCC that is forecasted between present conditions and the period between 2080 and 2099. We conclude that chemical property uncertainty does not preclude assessing relative changes in a GCC scenario compared to a present-day scenario if variance in model outputs due to chemical properties and degradation half-lives can be assumed to cancel out in the two scenarios. 相似文献
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The toxicity of naphthalene to a freshwater microalga, Chlorella pyrenoidosa, and the subsequent recovery of algae from the damage
were investigated under two nutrient conditions, either enriched with nitrogen (N) and phosphorus (P), or starved of N and P. Results
showed that C. pyrenoidosa was more sensitive to naphthalene under N,P-enriched condition, and the inhibitory rate generally increased
at first and then decreased gradually with the evaporation of naphthalene under both nutrient conditions. Enriched N, P reduced the
inhibitory rate at initial naphthalene concentration of 5 and 10 mg/L, but enhanced it at 100 mg/L, at which more severe ultrastructure
damages were found than those under N,P-starved condition. Observed damages included partly or totally disappearance of nucleolus,
nuclear, and plasma membranes. According to the chlorophyll content and cell density measurements, C. pyrenoidosa could recover
from naphthalene damage with initial concentrations 6 50 mg/L in 7 days under both nutrient conditions, while they could not recover
if the initial concentration of naphthalene was at 100 mg/L. Under the N,P-starved condition, the inability of C. pyrenoidosa to recover
from the naphthalene damage was consistent with the results of high inhibitory rate, low value of specific growth rate (SGR, 0.05
day??1), and the severe destruction of cell structure. However, under the N,P-enriched conditions, the observed lower inhibitory rate,
higher value of SGR (0.55 day??1), and the intact cell structure of most cells suggested that algae could potentially recover from the
naphthalene damage. 相似文献
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48.
生态系统健康与环境管理 总被引:26,自引:0,他引:26
环境管理和生态系统健康是密不可分的,生态系统健康是环境管理的目的,生态系统健康为环境管理提供了新的思路、新的方法,健康的生态系统为实现区域可持续发展提供技术支撑和发展基础.生态系统健康的发展演替过程是优化环境管理的步骤.优化的环境管理为生态系统健康发展提供宏观决策和社会经济保障.本文从学科发展的角度论述了生态系统健康产生的背景、理论基础和应用途径;从学科交叉的角度论述了生态系统健康的评价和与环境管理的关系.提出了环境管理的目标:健康的生态系统→健康的环境→健康的食品→健康的人类生态系统→健康的社会发展. 相似文献
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Liuwei Kong Min Hu Qinwen Tan Miao Feng Yu Qu Junling An Yuanhang Zhang Xingang Liu Nianliang Cheng 《环境科学学报(英文版)》2020,32(1):49-59
To clarify the aerosol hygroscopic growth and optical properties of the Pearl River Delta(PRD)region,integrated observations were conducted in Heshan City of Guangdong Province from October 19 to November 17,2014.The concentrations and chemical compositions of PM_(2.5),aerosol optical properties and meteorological parameters were measured.The mean value of PM_(2.5) increased from less than 35(excellent) to 35-75 μg/m~3(good) and then to greater than 75 μg/m~3(pollution),corresponding to mean PM_(2.5) values of 24.9,51.2,and 93.3 μg/m~3,respectively.The aerosol scattering hygroscopic growth factor(f(RH = 80%)) values were 2.0,2.12,and 2.18 for the excellent,good,and pollution levels,respectively.The atmospheric extinction coefficient(σext)and the absorption coefficient of aerosols(σ_(ap)) increased,and the single scattering albedo(SSA)decreased from the excellent to the pollution levels.For different air mass sources,under excellent and good levels,the land air mass from northern Heshan had lower f(RH) and σ_(sp) values.In addition,the mixed aerosol from the sea and coastal cities had lower f(RH) and showed that the local sources of coastal cities have higher scattering characteristics in pollution periods. 相似文献